TY - JOUR AB - This work illustrates ultrasound assisted synthesis of biodiesel from waste cooking oil using calcium diglyceroxide as a heterogeneous base catalyst. The effect of different variables such as methanol to oil molar ratio, catalyst loading, reaction temperature, ultrasonic power and duty cycle on the progress of the reaction was studied. Under the optimal reaction conditions viz. methanol to oil molar ratio 9:1, catalyst loading of 1% (w/w) of waste cooking oil, temperature 60 degrees C, low intensity ultrasonic power of 120W and 50% duty cycle, a maximum biodiesel yield of 93.5% was obtained. On the other hand, a conventional stirring method showed 65.6% yield for the similar reaction time of 30 min. It has been observed that the ultrasonic method was effective in terms of mass transfer, energy efficiency (1.083 x 10(-4) g/J), biodiesel yield and time reduction. The reusability of the catalyst under the optimal reaction conditions resulted in a decrease in the biodiesel yield. The kinetic studies of transesterification reaction have been carried out at different operating temperatures. The results revealed that the reaction followed second-order kinetics and the activation energy was found to be 119.23 kJ/mole. The biodiesel synthesized from the ultrasonic method has shown superior properties as compared to conventional method and also matched with the American Society for Testing and Materials (ASTM) standards. (C) 2015 Elsevier Ltd. All rights reserved. AD - Inst Chem Technol, Dept Chem Engn, Bombay 400019, Maharashtra, India AN - WOS:000357670100092 AU - Gupta, A. R. AU - Yadav, S. V. AU - Rathod, V. K. DA - Oct 15 DO - 10.1016/j.fuel.2015.05.064 J2 - Fuel KW - transesterification LA - English N1 - Cm4qq PY - 2015 SN - 0016-2361 SP - 800-806 ST - Enhancement in biodiesel production using waste cooking oil and calcium diglyceroxide as a heterogeneous catalyst in presence of ultrasound T2 - Fuel TI - Enhancement in biodiesel production using waste cooking oil and calcium diglyceroxide as a heterogeneous catalyst in presence of ultrasound UR - ://WOS:000357670100092 VL - 158 ID - 11280 ER -